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3:11
YouTube
Organic Chemistry with Lluís Llorens Palomo
Riley Oxidation
The Riley oxidation is the selenium dioxide-mediated oxidation of methylene groups to alpha ketones and at the allylic position of olefins. Reaction mechanism: 1. The oxidation begins with attack by the enol tautomer at the electrophilic selenium center. 2. Loss of water and attack at the alpha position by a second equivalent of water. 3 ...
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